Example Problem with Complete Solution

4F-4 : Heat & Work for a Closed Cycle Containing R-134a
8 pts
A piston-and-cylinder device contains R-134a which is initially at -10°C and 200 kPa.  The R-134a undergoes the following 3-step cycle :
                   
Step 1-2:   Isochoric heating to 80°C.          
Step 2-3:   Isothermal compression to a state in which the quality is 0.700Q23 = -85.6 kJ.
Step 3-1:   Adiabatic expansion.          
                   
a.) Carefully sketch the process path for this cycle on a PV Diagram.  Put a point on the diagram for each state.  Be sure to include and label all the important features for a complete PV diagram for this system.
 
b.) Determine Qcycle and Wcycle in kJ/kg.          
c.) Is this cycle a power cycle or a refrigeration cycle ?  Explain.      
                   
Read : We are given T1 and P1, so we can determine any and all properties of the system using the R-134a Tables.  In particular, we can evaluate the specific volume and we know that this does not chnge in step 1-2.  This gives us a 2nd intensive property for state 2 and allows us to evaluate all of the properties of state 2.  We expect T2 >T1.  Step 2-3 is an isothermal compression to a quality of x3 = 0.700.  Because T3 = T2, we will be able to evaluate all of the properties of state 3, again using the R-134a Tables.  In each of the three steps, we know the value of either the heat or the work.  W12 = 0 because the process is isochoric.  Q23 is given and Q31 = 0 because the process is adiabatic.  So, when we apply the 1st Law to each step, there is just one unknown and we can evaluate it.  Once we know Q and W for each step, we can determine Qcycle and Wcycle because they are the sum of the Q's and W's for the steps that make up the cycle, respectively.
Given : T1
-10
°C Find : Q12
???
kJ/kg
P1
200
kPa W23
???
kJ/kg
T2
80
°C W31
???
kJ/kg
T3
80
°C Qcycle
???
kJ/kg
x3
0.700
kg vap/kg Wcycle
???
kJ/kg
Q23
-85.6
kJ/kg
Q31
0
kJ
Diagrams : Figure 1.
Part a.) Figure 2.
Assumptions :
1 - Changes in kinetic and potential energies are negligible.
2 - Boundary work is the only form of work that crosses the system boundary.
Equations / Data / Solve :
Let's begin by writing the 1st Law for each of the three steps that make up the cycle, assuming that changes in potential and kinetic energy are negligible.
 
Step 1-2 : Equation. Eqn 1
Step 2-3 : Equation. Eqn 2
Step 3-1 : Equation. Eqn 3
Step 1-2 is isochoric, so no boundary work occurs.  If we assume that boundary work is the only form of work interaction in this cycle, then W12 = 0Q31 = 0 because step 3-1 is adiabatic.
We can solve Eqns 1 - 3 to evaluate the unknowns Q12, W23 and W31.
 
Step 1-2 : Equation. Eqn 4
Step 2-3 : Equation. Eqn 5
Step 3-1 : Equation. Eqn 6
Our next step must be to determine the value of the specific internal energy at states 1, 2 and 3 because, once we know these, we can use Eqns 4 - 6 to evaluate the unknowns Q12, W23 and W31.
Let's begin with state 1.  First, we must determine the phase or phases that exist in state 1.  We can accomplish this by comparing P1 to Psat(T1).
Psat(T1)
2633.2
kPa
Since P1 < Psat(T1), we conclude that a superheated vapor exists in the cylinder at state 1.
We can determine U1 from the Superheated R-134a Tables.  We can also determine V1 because we know V2 = V1 and the knowledge of this 2nd intensive variable for state 2 will allow us to evaluate U2.
V1 = V2 =
0.099915
m3/kg U1
224.56
kJ/kg
Next, let's work on state 2.  We know the value of 2 intensive variables, T2 and V2, and we know that if a superheated vapor expands at constant volume, it must still be a superheated vapor.  Consequently, we can use the Superheated R-134a Tables to determine U2 (and any other properties at state 2 that we want.
At T2 = 80°C, it turns out that V2 = 0.099915 m3/kg falls between 240 kPa and 280 kPa, so we must interpolate to determine U2.
At T2 = 80°C :
V
(m3/kg)
U
(kJ/kg)
P
(kPa)
0.11675
295.91
240
0.099915
U2
P2
U2
295.58
kJ/kg
0.099612
295.57
280
P2
279.29
kPa
Now, let's work on state 3.  We know the temperature and the quality, so we can determine U3 using :
Equation. Eqn 7
We can use the Saturated R-134a Tables to determine Usat vap and Usat liq at 80°C and then we can plug numbers into Eqn 7 to evaluate U3.
Usat liq
171.41
kJ/kg
Usat vap
263.69
kJ/kg

U3

236.0
kJ/kg
Now, we can go back and plug the values of the specific internal energies into Eqns 4 - 6 to evaluate the unknowns Q12, W23, and W31.
Q12
71.02
kJ/kg W23
-26.03
kJ/kg

W31

11.45
kJ/kg
Next, we need to evaluate the specific work and specific heat for the entire cycle.
The specific work for the cycle is the sum of the specific work for each step.
The specific amount of heat transfer for the cycle is the sum of the specific amount of heat transfer for each step.
Qcycle
-14.58
kJ/kg Wcycle
-14.58
kJ/kg
Verify: The assumptions made in this problem solution cannot be verified.
Answers:  
Q
(kJ/kg)
W
(kJ/kg)
Step 1 - 2
71.0
0
Step 1 - 3
-85.6
-26.0
Step 1 - 4
0
11.4
Cycle
-14.6
-14.6
Because Wcycle < 0, this is a refrigeration cycle !
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