Example Problem with Complete Solution

4F-1 : Heat and Work for a Cycle Carried Out in a Closed System 6 pts
A gas undergoes a thermodynamic cycle consisting of three quasi-equilibrium processes:
Process 1-2: constant volume, V = 0.028 m3, U2 - U1 = 26.4 kJ
Process 2-3: expansion with PV = constant, U3 = U2
Process 3-1: constant pressure, P = 1.4 bar, W31 = -10.5 kJ
               
Changes in kinetic and potential energies are negligible.
a.) Sketch the cycle on a PV Diagram.      
b.) Calculate the net work for the cycle, in kJ.
c.) Calculate the heat transfer for process 2-3, in kJ.
d.) Calculate the heat transfer for process 3-1, in kJ.
e.) Is this a power cycle or a refrigeration cycle ?
Given: Figure 1
Step 1-2:
V1 = V2 = 0.028 m3
U2 - U1 = 26.4 kJ
Step 2-3 P2 V2 = P3 V3
U3 = U2
Step 3-1: P3 = P1 = 140 kPa
W31 = -10.5 kJ
Find: Sketch the cycle on a PV Diagram.
Wcycle = kJ
Q23 = kJ
Q31 = kJ
Power or Refrigeration Cycle ?
Assumptions:
- The gas is a closed system
- Boundary work is the only form of work interaction
- Changes in kinetic and potential energies are negligible.
Part a.) Figure 1
Part b.) Since Wcycle = W12 + W23 + W31, we will work our way around the cycle and calculate each work term along the way.
Because the volume is constant in step 1-2: W12 = 0 kJ
In step 2-3: P V = C, therefore, the definition of boundary work becomes:
Equation 2
Eqn 1
But, we don't know V3 ! Perhaps we can use W31 to detemine V3.
Step 3-1 is isobaric, therefore, the definition of boundary work becomes:
Equation 3
Eqn 2
Solve this equation for V3 : Equation 4
Eqn 3
V3 = 0.103 m3
Now, plug V3 and C = P3V3 into Eqn 1 to determine W23:
W23 = 18.8 kJ
Sum the work terms for the three steps to get Wcycle:
Wcycle = 8.28 kJ
Part c.) Write the 1st Law for step 2-3: Q23 - W23 = U3 - U2 = 0 Eqn 4
W23 Q23 18.8 kJ
Part d.) Write the 1st Law for step 3-1: Q31 - W31 = U1 - U3 Eqn 5
But, U2 = U3 : Q31 - W31 = U1 - U3 = U1 - U2 = - ( U2 - U1 )
Eqn 6
Solve for Q31 : Q31 = W31  - ( U2 - U1 ) Eqn 7
Plug in the given values : Q31 = -36.9 kJ
Part e.) First, we should determine Q12 from the 1st Law:
Q12 - W12 = U2 - U1 = 0 Eqn 8
Q12 = U2 - U1 Eqn 9
Q12 = 26.4 kJ
Define: Qcycle = Q12 + Q23 + Q31 Eqn 10
Qcycle = 8.28 kJ
Since Qcycle > 0 and Wcycle > 0, this is a power cycle !
Notice that Qcycle = Wcycle because ΔUcycle = 0.
Thermal Efficiency is defined by : Equation 5
Eqn 11
hth 18.3%