Example Problem with Complete Solution

3C-2 : Application of the Gibbs Phase Rule to the Triple Point
2 pts
How many intensive variables can be independently specified at the triple point of water ?
Read : At the triple point, all three phases exist in equilibrium.
This is the unique aspect of the triple point and this problem.
Given : Number of chemical species present: C 1
Number of phases present at equilibrium: P 3
Equation : Gibbs Phase Rule : oFree = C - P + 2
Solve : oFree 0
NO intensive variables can be independently specified at the triple point !
This means that there is just one triple point and ALL of the properties of all of the phases are fixed !
The triple point is unique.